Simultaneous Determination of Signal and Background Asymmetries

نویسندگان

  • Jörg Pretz
  • Jean-Marc Le Goff
چکیده

This article discusses the determination of asymmetries. We consider a sample of events consisting of a peak of signal events on top of some background events. Both signal and background have an unknown asymmetry, e.g. a spin or forwardbackward asymmetry. A method is proposed which determines signal and background asymmetries simultaneously using event weighting. For vanishing asymmetries the statistical error of the asymmetries reaches the minimal variance bound (MVB) given by the Cramér-Rao inequality and it is very close to it for large asymmetries. The method thus provides a significant gain in statistics compared to the classical method of side band subtraction of background asymmetries. It has the advantage with respect to the unbinned maximum likelihood approach, reaching the MVB as well, that it does not require loops over the event sample in the minimization procedure.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Resolving Spectra Overlapping Based on Net Analyte Signal for Simultaneous Spectrophotometric Determination of Fluoxetine and Sertraline

The net analyte signal standard addition method was used for simultaneous spectrophotometric determination of sertraline and fluoxetine in pharmaceutical preparations. The method combines the advantages of the standard addition method with the net analyte signal concept to enable the extraction of information about an analyte from the spectra of multi-component mixtures. This method uses full s...

متن کامل

Simultaneous spectrophotometric determination of Rifampicin, Isoniazid and Pyrazinamide in a single step

Three antituberculosis medications are investigated in this work consist of rifampicin, isoniazid and pyrazinamide. The ultra violet (UV) spectra of these compounds are overlapped, thus use of suitable chemometric methods are helpful for simultaneous spectrophotometric determination of them. A generalized version of net analyte signal standard addition method (GNASSAM) was used for determinatio...

متن کامل

Simultaneous spectrophotometric determination of Rifampicin, Isoniazid and Pyrazinamide in a single step

Three antituberculosis medications are investigated in this work consist of rifampicin, isoniazid and pyrazinamide. The ultra violet (UV) spectra of these compounds are overlapped, thus use of suitable chemometric methods are helpful for simultaneous spectrophotometric determination of them. A generalized version of net analyte signal standard addition method (GNASSAM) was used for determinatio...

متن کامل

Wavelength region selection and spectrophotometric simultaneous determination of naphthol isomers based on net analyte signal

Naphthol isomers were simultaneously and spectrophotometrically determined in wastewater, using a model based on net analyte signal (NAS). The calibration method used is a variation of the original hybrid linear analysis method as proposed by Goicoechea and Olivieri (HLA/GO). Owing to spectral interferences, the simultaneous determination of mixtures of naphthol isomers, using a spectrophotomet...

متن کامل

Simultaneous Spectrophotometric Determination of Heavy Metal Ions Using Several Chemometrics Methods: Effect of Different Parameters of Savitzky-Golay and Direct Orthogonal Signal Correction Filters

Direct orthogonal signal correction(DOSC) and Savitzky-Golay filters (SGF) were applied as preprocessing methods on the original and first derivative absorbance data. Principle component regression (PCR), partial least squares (PLS) and iterative target transformation factor analysis (ITTFA), were used in spectrophotometric simultaneous determination of heavy divalent metal ions, l...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2009